Question
This theory classifies lead cations and aniline as intermediate species in its two namesake classes. For 10 points each:
[10m] Name this theory developed by Ralph Pearson that is important in transition metal chemistry. This theory sorts species based on polarizability, oxidation state, and atomic radius, among other factors.
ANSWER: HSAB theory [or hard soft acid base theory or hard and soft (Lewis) acid and base theory]
[10e] In HSAB theory, chemical potential is equal to the negative of this quantity on the Mulliken scale. This quantity is the tendency of an element to attract shared electrons in a bond.
ANSWER: electronegativity [prompt on chi]
[10h] In this rule implied by HSAB theory, the more electronegative nucleophile is used when the reaction has an SN1 (“S-N-one”) mechanism. It is named for a chemist who also names an oxidation reaction that converts an alkyl halide and a tosylate (“toss-ill-ate”) into a carbonyl.
ANSWER: Kornblum’s rule [accept Kornblum oxidation]
<Chemistry>
Summary
| 2024 ACF Regionals @ Berkeley | 01/27/2024 | Y | 3 | 20.00 | 67% | 100% | 33% |
| 2024 ACF Regionals @ Cornell | 01/27/2024 | Y | 2 | 10.00 | 100% | 0% | 0% |
| 2024 ACF Regionals @ JMU | 01/27/2024 | Y | 8 | 10.00 | 88% | 13% | 0% |
| 2024 ACF Regionals @ Minnesota | 01/27/2024 | Y | 2 | 15.00 | 100% | 50% | 0% |
| 2024 ACF Regionals @ Ohio State | 01/27/2024 | Y | 3 | 13.33 | 100% | 0% | 33% |
| 2024 ACF Regionals @ Rutgers | 01/27/2024 | Y | 5 | 16.00 | 100% | 40% | 20% |
| 2024 ACF Regionals @ Imperial | 01/27/2024 | Y | 8 | 11.25 | 75% | 25% | 13% |
| 2024 ACF Regionals @ Vanderbilt | 01/27/2024 | Y | 5 | 10.00 | 100% | 0% | 0% |
| 2024 ACF Regionals @ MIT | 01/27/2024 | Y | 3 | 13.33 | 100% | 33% | 0% |
Data
| Columbia A | NYU B | 10 | 10 | 10 | 30 |
| Haverford | Columbia C | 0 | 10 | 0 | 10 |
| NYU A | John Jay | 0 | 10 | 0 | 10 |
| Columbia B | Penn | 10 | 10 | 0 | 20 |
| Vassar | Rowan | 0 | 10 | 0 | 10 |