Question

Molecules with this property bind preferentially to ligands with even hapticity according to the Davies–Green–Mingos rules. An increase in this property due to lone pairs on atoms adjacent to a functional group of interest is described by the alpha effect. A reaction between an arene and a molecule with this property produces a reactive intermediate called the Meisenheimer complex. Solvents with this property react with their solutes in solvolysis reactions. A leaving group is kicked off an aromatic ring by a molecule with this property (-5[1])in the SNAr (“S-N-A-R”) mechanism. (10[2])Inversion of chiral symmetry occurs after a “backside attack” (10[1])from (10[1])a molecule with this property in SN2 reactions. For 10 points, name this property of molecules that can donate an electron pair (10[1])to an electrophile. ■END■ (10[3])

ANSWER: nucleophilicity [or nucleophiles; accept nucleophilic abstraction; accept nucleophilic aromatic substitution; accept Lewis bases or Lewis basic until read; prompt on bases or basic]
<Chemistry>
= Average correct buzz position

Back to tossups

Buzzes

PlayerTeamOpponentBuzz PositionValue
Brendan BethlehemCambridge BImperial B84-5
Oscar DespardCambridge ADurham B8810
Ian DewanKielEdinburgh8810
Sam MooreDurham ABristol9710
Justin LeeImperial ASheffield9810
Jacob RobertsonOxford ACambridge C12010
Ella WardeOxford BKCL12410
Dillon PatelWarwickOxford C12410
Carlos DoebeliImperial BCambridge B12410