Question
The D-site loses this structure due to distortion by Glu and Asp side chains in the mechanism of lysozyme. The Zimmerman-Traxler model predicts the aldol reaction's stereochemistry by assuming the transition state has this specific structure and analyzing the steric interactions. Transition states with this structure are thermodynamically favored for [3+3]-rearrangements like the Claisen and (*) Cope rearrangements. The Newman projection for this conformation is fully staggered, while it is fully gauche for a different conformation that experiences ■END■
ANSWER: chair conformation [prompt on ring or cyclic structure; prompt on cyclohexane]
<JZ, Chemistry>
= Average correct buzz position
Summary
2024 ARCADIA at Claremont | 2024-11-02 | Y | 3 | 100% | 0% | 33% | 94.00 |
2024 ARCADIA at Illinois | 2024-11-09 | Y | 4 | 75% | 0% | 50% | 104.33 |
2024 ARCADIA at Waterloo | 2024-11-09 | Y | 5 | 80% | 0% | 0% | 91.25 |
2024 ARCADIA at Penn State | 2024-12-06 | Y | 1 | 100% | 0% | 100% | 116.00 |
2024 ARCADIA at Florida Tech | 2024-12-06 | Y | 3 | 67% | 0% | 67% | 112.50 |
2024 ARCADIA at BU | 2024-12-06 | Y | 8 | 75% | 0% | 25% | 108.83 |
2024 ARCADIA at GT | 2024-12-06 | Y | 5 | 80% | 0% | 40% | 103.00 |
2024 ARCADIA at Warwick | 2024-12-06 | Y | 5 | 80% | 0% | 0% | 109.50 |
2024 ARCADIA at UC Berkeley | 2024-12-06 | Y | 2 | 100% | 50% | 0% | 67.00 |
2024 ARCADIA at Duke | 2024-12-06 | Y | 3 | 100% | 0% | 0% | 105.00 |
2024 ARCADIA at Missouri S&T | 2024-12-06 | Y | 2 | 100% | 0% | 0% | 98.50 |
2024 ARCADIA Online | 2025-05-17 | Y | 5 | 100% | 60% | 20% | 67.40 |
Buzzes
Player | Team | Opponent | Buzz Position | Value |
---|---|---|---|---|
Andrew Wang | Illinois Blue | Notre Dame | 26 | -5 |
Moses Kitakule | In the Mood for Buzz | bingy academy | 35 | 15 |
Hansen Jin | Berkeley B | Berkeley A | 35 | 15 |
Bryan Ugaz | ASU->Stanford->ASU pipeline | Social credit go vroom | 37 | 15 |
Jason Hong | Madmen and Specialists | she limp on my waltz till i feel pathetique | 40 | 15 |
Joy An | Harvard | Tufts A | 47 | -5 |
Shaun Iyer | Innovation Academy A | Georgia Tech C | 56 | -5 |
Aalok Bhattacharya | Boston College A | Tufts B | 65 | -5 |
Akshay Seetharam | Claremont | Anderson et al. | 65 | -5 |
Bill Zhao | UF B | UF C | 74 | -5 |
Ezra Santos | Chicago A | Purdue B | 76 | -5 |
Jason Cheng | Jason et al. | SGV Ventures | 76 | 10 |
Rohan Dalal | Georgia Tech A | Mississippi State | 77 | 10 |
Tiffany Zhou | UF A | UCF A | 79 | -5 |
Tony Chen | Toronto A | Toronto B | 80 | 10 |
Ishan Joshi | Toronto Metropolitan A | McMaster ApocolocyntosisBidii | 84 | 10 |
Richard Lin | Amherst | Clark House | 86 | 10 |
Cade Reinberger | RIT | Pitt | 86 | -5 |
Liam Kusalik | Waterloo Aspidistra | Waterloo Basic | 86 | 10 |
Jeremy Cummings | WashU | Truman | 88 | 10 |
Samarth Ram | Chicago B | Purdue A | 88 | 10 |
Benny Shtutman | South Carolina | Virginia Tech A | 90 | 10 |
Jonathan Haimowitz | ALCU | U[C]SD | 90 | 10 |
Ali Hamzeh | Toyota Tundra Turbos — Twisting Truths - Tackling Trivia - Taming Titans | Old and Young | 95 | -5 |
Michal Gerasimiuk | Stanford | Berkeley Past | 99 | 10 |
Zach Tseng | Georgia Tech D | Johns Creek | 101 | -5 |
Andy Huff | LSE B | Warwick B | 106 | 10 |
Richard Lim | Bowdoin C | Yale | 107 | 10 |
Darren Kellis | Milton | Innovation Academy B | 107 | 10 |
Shiv Seshan | Cambridge B | Imperial B | 107 | 10 |
Gabe Forrest | Squidward Community College | Missouri | 109 | 10 |
Joel Miles | Paddington in Peru (2024) | The cult of SGA | 109 | 10 |
Clete Reinberger | Valencia | USF | 109 | 10 |
Michael Hunding | Illinois Orange | SIUE | 109 | 10 |
Brendan Bethlehem | Cambridge A | Southampton | 109 | 10 |
Nathan Sheffield | MIT | Clark Wilson | 112 | 10 |
Rasheeq Azad | North Carolina B | Virginia Tech C | 112 | 10 |
Sanjay Shanmuga Perumal | Lambert | Innovation Academy C | 112 | 10 |
Asish Madarapu | North Carolina A | Virginia Tech B | 113 | 10 |
Asha Basu | McGill A | Carleton A | 115 | 10 |
Peter Scully | Tufts B | Boston College A | 116 | 10 |
Riley Roessler | Bowdoin B | Boston College B | 116 | 10 |
Dash Rumble | Bowdoin A | Brandeis B | 116 | 0 |
Cecile Thomas | Tufts A | Harvard | 116 | 10 |
Nathaniel Martin | Brandeis B | Bowdoin A | 116 | 0 |
Kai McFarland | BU | Brandeis A | 116 | 0 |
Jonathan Schnipper | Brandeis A | BU | 116 | 0 |
Young Fenimore Lee | Old and Young | Toyota Tundra Turbos — Twisting Truths - Tackling Trivia - Taming Titans | 116 | 10 |
Danny Peelen | Pitt | RIT | 116 | 10 |
Shiva Tegulla | UCF A | UF A | 116 | 10 |
Nicholas Nguyen | UF C | UF B | 116 | 0 |
Xavier Spano | Waterloo Cloze | Toronto Chestnut Rice and Kamehameha | 116 | 0 |
Joey Sun | Toronto Chestnut Rice and Kamehameha | Waterloo Cloze | 116 | 0 |
Moses Dong | Johns Creek | Georgia Tech D | 116 | 10 |
Zach Joseph | Notre Dame | Illinois Blue | 116 | 10 |
Owyn Noble | Purdue B | Chicago A | 116 | 0 |
Chris Levesley | Warwick A | Imperial A | 116 | 10 |
Tobin Payne | Warwick C | LSE A | 116 | 0 |
Ian Tullis | Anderson et al. | Claremont | 116 | 10 |