Question

A semi-empirical method that eliminates three- and four-center two-electron integrals is named for the “neglect” of one form of this phenomenon. For the H2+ (“H-2-plus”) ion, a pair of energies are given by “H-AA plus H-AB over quantity one plus” a measure of this phenomenon. Roothaan (“ROTE-hahn”) simplified the Hartree–Fock method into the equation “FC equals SC epsilon,” where S is a matrix named for this phenomenon. (10[1]-5[1])For two (10[1])wavefunctions, this phenomenon is described by the integral (-5[1])over all volume of “psi-A-star times psi-B,” (10[1]-5[1])which vanishes for orthogonal orbitals like p-x and p-y. A pair (10[1])of atomic orbitals (-5[1])for which this phenomenon (-5[1])is higher will have more stabilized (-5[1])bonding molecular (10[1])orbitals. (10[1])Sigma bonds form when this phenomenon (-5[1])is (10[1])end-on. (10[1]-5[1])For 10 points, (10[1])name this phenomenon (-5[1])in which (10[1])space is shared (10[1])by (-5[1])two orbitals. (10[2])■END■ (10[9]0[24])

ANSWER: orbital overlap [accept neglect of diatomic differential overlap; accept overlap matrix or overlap integral; reject “hybridization”]
<Chemistry>
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PlayerTeamOpponentBuzz PositionValue
David BassJohns HopkinsPenn64-5
Jacob RobertsonOxford AOxford B6410
Rasheeq Azad (UG)UNC B (UG)UNC A (Grad)6610
Justin LeeImperial AWarwick74-5
Chinmay MurthyTexas AIowa A81-5
Rachel BenthamCambridge BEdinburgh8110
Maxwell YeCambridge ADurham A9210
Jason Qin (DII)Columbia CNYU A95-5
Rohan DalalGeorgia Tech BHarding99-5
Brian Lai (DII)Virginia B (UG)Liberty B (DII)105-5
JD KrothIowa StateMinnesota B10710
Noah ChenColumbia BColumbia A10810
Yared TadesseCornell ARIT B114-5
Jaime Salamanca CamachoImperial BCambridge C11510
Alexander HarmataMichigan AOhio State A11610
Gavin MarkoffVanderbilt AGeorgia Tech A116-5
Yashodev VyasMinnesota CArizona State11910
Caleb WestKentuckyTennessee122-5
Lewys JenkinsBristolDurham B12410
Akshay SeetharamClaremont AMichigan State A12710
Joseph Chambers (DII)Virginia A (UG)Maryland A (Grad)128-5
Jerry VinokurovJohn JayRowan13010
Arunn SankarGeorgia Tech AVanderbilt A13010
Cade ReinbergerRIT BCornell A13110
Karthik PrasadCornell BRIT A1310
Danny CutbillRIT ACornell B1310
Miller Doer (DII)Liberty C (DII)JMU A (UG)1310
Vedang Singhal (DII)UNC D (DII)GWU B (Grad)1310
Addie King (UG)JMU A (UG)Liberty C (DII)1310
Ethan Cohen (UG)GWU A (UG)Maryland B (UG)1310
Munir Siddiqui (UG)Maryland B (UG)GWU A (UG)1310
Brian Dudley (UG)William & Mary A (UG)Maryland C (DII)1310
Logan Mitchell (UG)JMU B (UG)Roanoke College A (DII)1310
Joshua Schmidt (DII)Liberty B (DII)Virginia B (UG)13110
Michael Eng (UG)UNC C (UG)Liberty A (Grad)13110
Shantanu ThoratTexas A&M AAppalachian State1310
Kathy LiangRice AIowa B1310
Cormac BeirneSorbonneUW A1310
Anwitha VempaliIowa BRice A1310
Russell NipUBC ATexas A&M B13110
Isaac OlsonUW ASorbonne13110
Cameron WilliamsAppalachian StateTexas A&M A1310
Grace EarlyIowa ATexas A13110
Jacob Goodson (DII)Ohio State BCedarville1310
Dennis Yang (DII)Michigan BKenyon1310
Iris Pardue (UG)KenyonMichigan B1310
Emmett Bicknell (DII)CedarvilleOhio State B1310
Halle FriedmanNYU AColumbia C1310
Vishal Kanigcherla (UG)PennJohns Hopkins13110
Eve Andersen (UG)VassarNYU B1310
Ian DewanKielKCL13110
Freddy PottsSheffieldOxford C1310
Matt SheldonOxford CSheffield1310
Sarah PatelVanderbilt BAlabama1310
Khushi UmarwadiaSouth CarolinaGeodesic13110
Davin SivertsonAlabamaVanderbilt B1310