A derivative of one of these compounds contains additional dimethyl amino and acetate groups and is sold as ellaOne. Russell E. Marker synthesized one of these compounds by degrading diosgenin. The “suppression” of one of these compounds is measured in a test in which patients ingest a pill containing dexamethasone the night before. A natural precursor to one of these compounds is formed by four concerted cationic cyclization reactions from squalene epoxide. Premarin is a conjugated equine type of these compounds that is sulfated on the A ring of their ABCD classification system. The adrenal cortex produces a class of these compounds prefixed by “mineral” and “gluco.” For 10 points, name these lipids with four fused rings, the skeleton of most sex hormones. ■END■
ANSWER: steroids [accept steroid hormones; accept sterols or cholesterol or lanosterol or 24-dehydrocholesterol; accept sex hormones until read; accept progesterone or estrogen or estradiol; accept Premarin until read; accept conjugated estrogens or CEs or conjugated equine estrogens or CEEs; accept cortisol or corticoids or mineralocorticoids or glucocorticoids or corticosteroids; accept dexamethasone until read; prompt on hormones; prompt on lipids or fats; prompt on terpenes or terpenoids or isoprenoids; prompt on combined oral contraceptives or emergency contraception or birth control pills by asking “what class of compounds are active?”; reject “phospholipids”] (The first sentence refers to ulipristal acetate.)
<Durham A, Chemistry>
= Average correct buzz position