Question
In 2012, Byrne and Gilheany affirmed this reaction progresses differently in salt-containing and salt-free conditions, with the latter scenario being susceptible to “stereochemical drift.” In one mechanism, this reaction begins with a [2+2] cycloaddition followed by a fragmentation step. One reagent is replaced with a resonance-stabilized ester carbanion in a variant of this reaction partly named for Leopold Horner. In a modification to this reaction, the use of (*) phenyllithium leads to the preferential formation of (E)-isomers. This reaction’s intermediate exists in an equilibrium between betaine (“bay-tah-een”) and oxaphosphetane (“ock-sah-FOSS-fuh-tain”) forms. This is the most popular reaction used to convert a carbonyl into an alkene. A German chemist names, for 10 points, what reaction that makes use of triphenyl phosphonium ylide reagents? ■END■
Buzzes
Player | Team | Opponent | Buzz Position | Value |
---|---|---|---|---|
Eric Mukherjee | Ill-Advised Buzz | bruh | 26 | 15 |
Tracy Mirkin | Statler and Waldorfesque Former Penn Bowl Editors | Khalil v Carbolic Shisha Ball Co | 61 | 15 |
Stephen Liu | We jopping | Oh you like geography? Name every Forrest. | 65 | 15 |
Dan Ni | TOAD | Why the Kremlin Hates Bananas | 84 | 10 |