When using a given basis set, both energy and this quantity are multiplied by a dimensionless scaling factor usually close to 1 to account for a term called ZPVE. For a transition state, this quantity takes on an imaginary value since it corresponds to a negative eigenvalue of the mass-weighted Hessian of a Born-Oppenheimer surface. Olfactory receptors identify molecules by their value for this quantity, according to the controversial (*) "swipe card model." Heavy isotopologues have lowered values of this quantity, lowering the rate constant in the kinetic isotope effect. For a covalent bond modeled as a Hookean spring, this quantity is (read slowly) one over two pi times the square root of force constant over reduced mass. For 10 points, name this quantity that describes the rate at which an atom in a molecule oscillates, measured in hertz. ■END■
ANSWER: vibrational frequency [or resonance frequency; or harmonic vibrational frequency; accept answers referring to the frequency of (molecular) vibrations or bond oscillations; prompt on frequency or f or nu with "frequency of what?"]
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