Question
The Cope rearrangement is a [3, 3]-sigmatropic rearrangement of one of these molecules. For 10 points each:
[10h] Name these molecules. In one reaction, groups at the 2 and 5 position of one of these molecules are on the same side of the ring as an EWG in the endo transition state.
ANSWER: dienes [accept diolefins]
[10m] The endo transition state is favored in the Diels-Alder reaction, a [4+2] [four plus two] example of this type of reaction where two components form a ring and decrease the bond multiplicity.
ANSWER: cycloaddition [prompt on addition reaction or pericyclic reaction]
[10e] The Diels-Alder reaction can be catalyzed with these proton-donating molecules. Solutions with these molecules have a pH below 7.
ANSWER: acids
<Science - Chemistry>
Summary
| 2024 Booster Shot (Columbia) | 02/23/2024 | Y | 6 | 16.67 | 100% | 50% | 17% |
| 2024 Booster Shot (Great Lakes) | 03/09/2024 | Y | 6 | 16.67 | 100% | 50% | 17% |
| 2024 Booster Shot (Vanderbilt) | 03/02/2024 | Y | 4 | 12.50 | 75% | 50% | 0% |
| 2024 Booster Shot (WUSTL) | 03/09/2024 | Y | 3 | 16.67 | 100% | 67% | 0% |
| 2024 Booster Shot (Waterloo) | 02/23/2024 | Y | 4 | 17.50 | 100% | 75% | 0% |
Data
| MTSU | Belmont | 0 | 10 | 0 | 10 |
| WUSTL | Georgia Tech C | 0 | 10 | 10 | 20 |
| USN A | Georgia Tech B | 0 | 0 | 10 | 10 |
| Vanderbilt B | Claremont | 0 | 0 | 10 | 10 |