Question

In 2012, Byrne and Gilheany affirmed this reaction progresses differently in salt-containing and salt-free conditions, with the latter scenario being susceptible to “stereochemical drift.” A [2+2] cycloaddition begins one of this reaction’s two mechanisms that sees the formation of a “closed” four-membered ring intermediate. One reagent is replaced with an ester carbanion in a variant of this reaction partly named for Leopold Horner. This reaction’s intermediate exists in an equilibrium between (*) betaine (“bay-tah-een”) and oxaphosphetane (“ock-sah-FOSS-fuh-tain”) forms. (10[1])Phenyllithium aids in the preferential formation of (E)-isomers in this reaction’s (10[1])Schlosser modification. This is the most popular reaction used to convert a carbonyl into an alkene. A German chemist names, for 10 points, what reaction that makes use of triphenyl phosphonium ylide reagents? ■END■

ANSWER: Wittig reaction [or Wittig olefination; accept Wittig reagent; accept Horner-Wadsworth-Emmons reaction or HWE reaction until “Horner” is read]
<Kane Nguyen, Chemistry>
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Buzzes

PlayerTeamOpponentBuzz PositionValue
Tim MorrisonStanfordBerkeley A7410
Shahar SchwartzBerkeley CBerkeley B8510

Summary

2024 Penn Bowl Berkeley11/02/2024Y2100%0%0%79.50
2024 Penn Bowl CWRU11/02/2024Y425%0%0%119.00
2024 Penn Bowl Chicago11/02/2024Y888%38%25%82.14
2024 Penn Bowl Mainsite11/02/2024Y367%0%33%117.00
2024 Penn Bowl Texas11/02/2024Y250%0%0%116.00