Question

This molecule composed of excited atoms was the first observed Rydberg molecule. For 10 points each:
[10h] Name this molecule, whose fully filled sigma-1s and sigma-star-1s molecular orbitals with no other MOs give it a bond order of zero. This molecule’s bond length of 5200 picometers makes it the largest diatomic molecule.
ANSWER: dihelium [or helium dimer; or He2; reject “helium”]
[10e] Despite having zero bond order in MO theory, dihelium is held together very weakly by these intermolecular forces named for a Dutch physicist. London dispersion and dipole-dipole interactions contribute to these forces.
ANSWER: van der Waals forces
[10m] Dihelium molecules have been observed to fit inside these other compounds in a host-guest relationship. These allotropes are denoted with the formula C-sub-x, where x is the number of atoms within the compound.
ANSWER: fullerenes [accept buckminsterfullerenes or buckyballs]
<Chemistry>

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Summary

Data

Indiana BWashU D010010
Purdue AMiami0101020
WashU BNorthwestern A0101020
UChicago CNotre Dame0101020
Indiana APurdue C010010
Purdue DUChicago B010010
UIUC ASIUE A010010
UIUC CUChicago D010010
UChicago AWashU C0101020