In one reaction, a pi-allyl complex containing this element undergoes a Walden inversion in an oxidative addition step that allows a nucleophile to substitute an alkene. Barium sulfate poisons this element in a reduction reaction that produces aldehydes. Reducing an acetate with phosphine activates this element in one reaction, and this element is regenerated by copper chloride to catalyze the oxidation of ethylene into acetaldehyde during the (*) Wacker process. This element catalyzes a reaction that forms carbon-carbon bonds with an organoboron species and a halide. Heck, Negishi, and Suzuki won the 2010 Nobel Prize in Chemistry for work on cross-coupling reactions catalyzed by this metal. For 10 points, name this expensive platinum-group metal found in Lindlar’s catalyst, with symbol Pd. ■END■
| 2025 Penn Bowl - Stanford | 10/25/25 | Y | 4 | 100% | 25% | 0% | 72.00 |
| 2025 Penn Bowl - Northwestern | 10/25/25 | Y | 4 | 100% | 25% | 0% | 84.25 |
| 2025 Penn Bowl - Mainsite (UPenn) | 11/01/25 | Y | 6 | 100% | 67% | 17% | 67.00 |
| 2025 Penn Bowl - BU | 11/01/25 | Y | 4 | 100% | 0% | 50% | 104.50 |
| 2025 Penn Bowl - CWRU | 11/01/25 | Y | 3 | 67% | 0% | 100% | 120.00 |
| 2025 Penn Bowl - UNC | 11/01/25 | Y | 3 | 100% | 0% | 33% | 105.67 |
| 2025 Penn Bowl - WashU | 11/01/25 | Y | 2 | 100% | 50% | 0% | 68.50 |
| 2025 Penn Bowl - Ottawa | 11/01/25 | Y | 7 | 100% | 14% | 14% | 93.57 |
| 2025 Penn Bowl - UK | 11/01/25 | Y | 9 | 100% | 22% | 11% | 89.22 |
| 2025 Penn Bowl - Online | 11/08/25 | Y | 2 | 100% | 0% | 50% | 113.50 |
| 2025 Penn Bowl - Murray State | 11/08/25 | Y | 2 | 100% | 50% | 0% | 87.50 |
| Player | Team | Opponent | Buzz Position | Value |
|---|---|---|---|---|
| Matthew Schiavone | Northwestern A | Illinois | 30 | 15 |
| Richard Niu | The best time to buzz was twenty clues ago. The second best time to buzz is now | Berkeley B | 30 | 15 |
| Caleb Ott | Waterloo you are crooked | Toronto G | 30 | 15 |
| Moses Kitakule | Columbia A | JHU B | 32 | 15 |
| Aneesh Swaminathan | JHU A | Swarthmore | 34 | 15 |
| Olin Bose | Columbia B | John Jay | 36 | 15 |
| Ben Russell Jones | Burnaburiash's Lapis Lazuli | To buzz is to be perceived | 36 | 15 |
| Paul Lee | WashU Bouba | WashU Kiki | 36 | 15 |
| Matthew He | Texas B | Central Oklahoma | 55 | 15 |
| Ryan Rosenberg | NYU A | Maryland B | 60 | 15 |
| Christopher Bradley | rusty shackleford | Wake Up Paddington A Washington Mystery | 62 | -5 |
| Evan Lynch | Washed Scrubs | Penn and the Art of Tossup-Bonus cycle Maintenance | 64 | 15 |
| Sam Moore | Knorr Stock Clue | Chimp Brisket | 68 | 10 |
| Charlie Ruff | McGill Fartlets | Toronto Murder on the Rider Express | 80 | 10 |
| Tanay Bodducherla | Berkeley C | In Search of Lost Clues | 80 | 10 |
| Pace Klein | CWRU | Ohio State A | 81 | -5 |
| Ilyas Choukri | VT A | UNC B | 81 | 10 |
| Mason Yu | Brown | RIT | 86 | 10 |
| Swapnil Garg | Berkeley A | Stanford B | 87 | 10 |
| Coby Tran | UChicago B | Purdue A | 88 | 10 |
| Allan Lee | Stanford A | Free Win | 91 | 10 |
| Eugenia Tong | The Bit and the Penndulum | Paul Quifford, or, It Was a Dark and Stormy Tournament | 91 | 10 |
| Brendan Bridle | Queen's is monitoring the situation | Toronto Sunshine Bubbles | 92 | 10 |
| Vivek Sasse | Hail to the Sheaf | Alas poor Warwick, I knew him Edinburgh | 92 | 10 |
| Nathan Sheffield | MIT A | I've been running into you in my lead plumbocene what could have benzene | 92 | 10 |
| Nathan Long | Quiztian Bale in Ratman Begins | Coughing Baby | 92 | 10 |
| Jason Zhang | Toronto Operation PBSuccess | Carleton A | 93 | -5 |
| Fern Fang | Planck Sinatra | UNC A | 94 | -5 |
| Rachel Bentham | question mark | Galactic Ombudsmen | 99 | -5 |
| Alex Akridge | Indiana | Purdue B | 100 | 10 |
| Neal Joshi | VJ Edgecombe School of Interior Design - Edwardsville | Truman State | 101 | 10 |
| Rachel Fanous | Michigan A | Michigan B | 104 | -5 |
| Michael Kearney | Harvard | Yale | 104 | -5 |
| Aatreyo Bhattacharyya | abg academy | New Young Whigs of America | 107 | 10 |
| Maude-Sophie Lockman | Aweille Kevin Fan osti continue comme ça | Guelph perfomative male competition | 108 | 10 |
| Jacob Goodson | Ohio State B | Michigan C | 112 | -5 |
| Kelvin Ni | NYU B | Mount Sinai | 112 | -5 |
| Colin Veevers | Ottawa 67s | McGill B | 112 | 10 |
| Peter Breggren | MIT B | Brandeis | 113 | -5 |
| Alec Zelek | Toronto E | #OpenToBuzz | 113 | 10 |
| Emily Kadolph | VT B | Wise Duke | 116 | 10 |
| Owen Eskey | Northwestern B | UChicago C | 119 | 10 |
| Aditya Patnaik | Ohio State A | CWRU | 120 | 10 |
| Josh Koch | Michigan B | Michigan A | 120 | 0 |
| Reed Sexton | Michigan C | Ohio State B | 120 | 10 |
| Simarya Ahuja | Wake Up Paddington A Washington Mystery | rusty shackleford | 120 | 10 |
| Christopher Dech | Brandeis | MIT B | 120 | 10 |
| William Orr | Yale | Harvard | 120 | 10 |
| Jonathan Lau | Maryland A | Maryland C | 120 | 10 |
| Daniel Ma | Mount Sinai | NYU B | 120 | 10 |
| Bryce Cruise | Texas A | Oklahoma | 120 | 10 |
| Ethan Webb | Of Mice and Penn | Bristold | 120 | 10 |
| Nick Smemoe | UNC A | Planck Sinatra | 120 | 10 |
| Oliver West | Galactic Ombudsmen | question mark | 120 | 10 |
| Abdelrahman Elsisi | why is it called a score clue if nobody scores points on it | 1. Wawa 2. Blank Street 151. Black Sheep at Kings Cross rail | 120 | 10 |
| Kevin Le | Carleton A | Toronto Operation PBSuccess | 120 | 10 |