Question
Some zinc-containing batteries use an unusual tetroxide of this element containing cations in the plus-one and plus-three oxidation states. For 10 points each:
[10m] Name this element whose plus-one cation is central in a diamine complex that precipitates out upon acting as an oxidizing agent. This element’s nitrate is used as a test for chloride ions.
ANSWER: silver [or Ag]
[10e] The formation of a “silver mirror” is a positive result in Tollens’ test, which distinguishes types of this functional group defined by a C–O double bond.
ANSWER: carbonyl [accept aldehyde or ketone]
[10h] Silver(I) (“silver one”) catalysts are a common choice for this reaction that starts with a diazoketone. This reaction’s ketene intermediate can undergo a two-plus-two cycloaddition to form a four-membered ring.
ANSWER: Wolff rearrangement [prompt on rearrangement]
<WashU B, Chemistry>
Summary
| California | 2025-02-01 | Y | 3 | 10.00 | 67% | 33% | 0% |
| Great Lakes | 2025-02-01 | Y | 5 | 8.00 | 60% | 20% | 0% |
| Lower Mid-Atlantic | 2025-02-01 | Y | 6 | 6.67 | 50% | 17% | 0% |
| Midwest | 2025-02-01 | Y | 6 | 15.00 | 100% | 50% | 0% |
| North | 2025-02-01 | Y | 3 | 10.00 | 67% | 33% | 0% |
| Overflow | 2025-02-01 | Y | 5 | 10.00 | 60% | 40% | 0% |
| Pacific Northwest | 2025-02-01 | Y | 2 | 20.00 | 100% | 100% | 0% |
| South Central | 2025-02-01 | Y | 2 | 15.00 | 50% | 100% | 0% |
| Southeast | 2025-02-01 | Y | 4 | 10.00 | 75% | 25% | 0% |
| UK | 2025-02-01 | Y | 10 | 13.00 | 40% | 70% | 20% |
| Upper Mid-Atlantic | 2025-02-01 | Y | 8 | 13.75 | 88% | 50% | 0% |
| Upstate NY | 2025-02-01 | Y | 3 | 6.67 | 67% | 0% | 0% |
Data
| Claremont A | UCLA | 0 | 10 | 0 | 10 |
| Claremont B | UC Berkeley A | 0 | 0 | 0 | 0 |
| UC Berkeley B | UCSD | 10 | 10 | 0 | 20 |
| Carnegie Mellon A | Ohio State A | 0 | 10 | 0 | 10 |
| Michigan D | Carnegie Mellon B | 0 | 0 | 0 | 0 |
| Case Western B | Case Western A | 10 | 10 | 0 | 20 |
| Michigan A | Michigan State | 0 | 10 | 0 | 10 |
| Ohio State B | Kenyon | 0 | 0 | 0 | 0 |
| Chicago B | Chicago A | 10 | 10 | 0 | 20 |
| Chicago D | Missouri S&T | 10 | 10 | 0 | 20 |
| Illinois B | Indiana B | 0 | 10 | 0 | 10 |
| WashU A | Illinois C | 10 | 10 | 0 | 20 |
| Illinois A | Indiana A | 0 | 10 | 0 | 10 |
| Chicago C | Missouri | 0 | 10 | 0 | 10 |
| William & Mary | Duke | 0 | 10 | 0 | 10 |
| UNC B | Liberty A | 0 | 10 | 0 | 10 |
| Liberty C | UNC D | 10 | 0 | 0 | 10 |
| South Carolina | Virginia Tech A | 0 | 10 | 0 | 10 |
| Liberty B | UNC C | 0 | 0 | 0 | 0 |
| Virginia A | Wake Forest | 0 | 0 | 0 | 0 |
| Carleton | Wisconsin A | 0 | 0 | 0 | 0 |
| Iowa State | Winona State | 10 | 10 | 0 | 20 |
| Minnesota B | Wisconsin B | 0 | 10 | 0 | 10 |
| Georgetown A | Stanford B | 0 | 0 | 0 | 0 |
| Georgetown B | Northwestern A | 0 | 0 | 0 | 0 |
| Iowa | Notre Dame B | 0 | 10 | 0 | 10 |
| Purdue | Northwestern B | 10 | 10 | 0 | 20 |
| Notre Dame A | Notre Dame C | 10 | 10 | 0 | 20 |
| Alberta | UW A | 10 | 10 | 0 | 20 |
| UBC | UW B | 10 | 10 | 0 | 20 |
| Georgia Tech C | Alabama A | 10 | 10 | 0 | 20 |
| Louisville A | Vanderbilt A | 0 | 0 | 0 | 0 |
| Georgia Tech D | Tennessee A | 0 | 10 | 0 | 10 |
| Bruin A | Georgia Tech B | 0 | 10 | 0 | 10 |
| Oxford B | Cambridge A | 0 | 0 | 0 | 0 |
| Cambridge E | Cambridge C | 10 | 10 | 0 | 20 |
| Cambridge B | Cambridge D | 10 | 0 | 0 | 10 |
| Imperial A | Durham | 10 | 10 | 0 | 20 |
| LSE | Imperial B | 10 | 0 | 10 | 20 |
| Manchester | Warwick A | 10 | 10 | 0 | 20 |
| Oxford A | Warwick B | 10 | 0 | 10 | 20 |
| Southampton A | Oxford C | 0 | 0 | 0 | 0 |
| Bristol | Sheffield | 0 | 0 | 0 | 0 |
| Southampton B | NYU C | 10 | 10 | 0 | 20 |
| Columbia B | Haverford B | 10 | 10 | 0 | 20 |
| Cornell B | Columbia C | 10 | 10 | 0 | 20 |
| NYU A | John Jay College | 10 | 10 | 0 | 20 |
| Johns Hopkins A | Rutgers A | 0 | 10 | 0 | 10 |
| Maryland B | Penn B | 0 | 0 | 0 | 0 |
| NYU B | George Washington A | 0 | 10 | 0 | 10 |
| Penn A | George Washington B | 10 | 10 | 0 | 20 |
| Yale A | Vassar A | 0 | 10 | 0 | 10 |
| TAMU | Texas A | 10 | 0 | 0 | 10 |
| ASU | Texas B | 10 | 10 | 0 | 20 |
| ESF A | Cornell D | 0 | 0 | 0 | 0 |
| RIT A | Cornell C | 0 | 10 | 0 | 10 |
| Binghamton A | RIT B | 0 | 10 | 0 | 10 |