Question

This theory accounts for long-range interactions in the ePC–SAFT equation. Assumption of the validity of this theory allows one to derive the expression of the rate constant in the kinetic salt effect. An “extended” version of this theory is given by the Truesdell–Jones equation, which when modified by an extra term gives the Davies equation. (10[1])It’s not DVLO, but the thickness of the electrical double layer (10[1])follows from this theory, which was modified to reconcile with the empirical Kohlrausch’s law by Lars Onsager. This theory is derived from (10[1])linearizing the Poisson–Boltzmann equation. (10[3])This theory’s “limiting law” predicts that a quantity denoted lowercase gamma varies with the (10[1])square root of ionic strength (10[1])at very low concentrations. (10[1])For 10 points, (10[2])name this doubly-eponymous (10[3])theory (10[1]-5[1])that predicts activity coefficients in dilute (-5[1])solutions. ■END■ (10[2]0[9])

ANSWER: Debye–Hückel theory [or Debye–Hückel equation; accept Debye–Hückel–Onsager equation; accept Debye-Hückel limiting law]
<Chemistry>
= Average correct buzz position

Summary

2025 ACF Nationals04/19/2025Y2277%0%9%104.76

Buzzes

PlayerTeamOpponentBuzz PositionValue
Adam FineChicago AColumbia A5410
Andrew WangIllinois ANYU6510
Tony ChenToronto AArizona State8710
Nikhil ChellamNorthwesternGeorgia State9110
Tim MorrisonStanfordJohns Hopkins9110
Alex AkridgeIndianaMIT9110
Liam KusalikWaterloo AVanderbilt10510
James WangOttawaHarvard11010
Jason ZhangToronto CChicago B11410
Swapnil GargUC Berkeley ANorth Carolina B11710
Shiva TegullaUCFUC Berkeley B11710
Caleb OttWaterloo BColumbia B12010
Russell NipBritish ColumbiaWUSTL B12010
Calvin BostlemanOhio StateVirginia Tech12010
Karan GurazadaTexasGeorgia Tech12110
Guy IndoranteIowa StateIllinois B121-5
Neal JoshiWUSTL AFlorida127-5
Yash MandaviaIllinois BIowa State1290
Teigue KellyPenn StateVirginia1290
Kunaal ChandrashekarToronto BMichigan1290
Kushal AluruRutgersRIT1290
Cade ReinbergerRITRutgers12910
Leo LawFloridaWUSTL A12910
Yashwanth BajjiMichiganToronto B1290
Andy HuffLSEMaryland1290
Andy YuMarylandLSE1290
Joel MilesMinnesotaWinona State1290
Joseph ChambersVirginiaPenn State1290