This man is the first of two scientists who name an inequality that uses the time derivative of specific internal energy and Cauchy stress by incorporating energy conservation. It’s not Gibbs, but that inequality shows that dissipation in real materials is always positive and is named after this scientist and Duhem. The sum of the changes in heat and enthalpy are used in this scientist’s early formulation of (*) disgregation. This scientist names his now-abandoned unit of one calorie per degree Celsius or 4.19 Joules per Kelvin. This scientist’s namesake theorem states that the integral of d-S is always non-negative, (10[1])a mathematical reformulation of the second law of thermodynamics. For 10 points, name this German physicist who gave the first mathematical (-5[1])definition of entropy. ■END■ (10[1]0[3])