Question

This compound or a cyclic relative is boiled when converting aromatic chlorides to fluorides in the Halex process. This is the simplest compound that can be activated by acetic anhydride in the Pummerer rearrangement. A “d6” derivative of this amphiphilic compound is often mixed with similar analogs of dichloromethane and chloroform to reduce its viscosity. This compound can be added to master mixes at 3 percent to inhibit secondary structures and decrease the (*) annealing temperature of GC-rich templates in PCR. (-5[1])The deuterated form of this compound shows a residual quintet peak at 2.50 ppm (10[1]-5[1])in proton NMR. This compound has a much higher boiling point than acetone, while only being different (10[1])at its central (10[1])atom. This polar (10[1])aprotic (10[1])solvent (-5[1])is rapidly (10[1])absorbed (10[1])by skin and leaves a taste of garlic. (10[2])For 10 points, name this organic solvent (10[1])that consists of two methyl groups and an oxygen double bonded to a central (10[1])sulfur atom. ■END■ (10[3]0[2])

ANSWER: DMSO [or dimethyl sulfoxide; accept deuterated DMSO or dimethyl sulfoxide-d6; prompt on DMF or dimethylformamide until “Pummerer” is read by asking “what is the other non-cyclic solvent commonly used?”] (The cyclic relative is sulfolane, another polar aprotic solvent with an oxygen–sulfur double bond.)
<KP, Chemistry>
= Average correct buzz position

Summary

2024 Chicago Open07/28/2024Y1593%0%20%128.07

Buzzes

PlayerTeamOpponentBuzz PositionValue
Walter ZhaoRead slowly: A A A A A A A A A A A A A A A Read quickly: ACharlotte's Moderately Successful Team79-5
Eric MukherjeeLMM's LLM MLMI’ll take a quiet 10 / A handshake of CO (Chicago Open)9310
Kevin WanggenAI this, genAI that, have you found your 真爱 yetvar merchants93-5
Gautam Kandlikarwhen you look this good, you don’t have to know anythingNJTRANSit (and anwen, I guess)11010
Billy BusseBHSU BThe Dyatlov Passement incident11310
Ethan AshbrookGalvanized Square Steen and Eco-Friendly Wood VermeerThe Oldest Men in the World11610
Daniel MaThere are buzzable clues everywhere for those with eyes to seeNJTRANSit (and bobby, i guess)11710
Richard NiuAMOGH QUIZ HACK? 英雄联盟 400 PPG 24 TUHLisan al-Quib118-5
Swapnil Gargit's the great pumpkinification objection, charlie brownWe Need New Names12010
Vincent DuA Nervy Liberal Nanny Hencesticking out your guyot for the ridge push; you're so seafloor spread, you're so fracture zone12110
Kai SmithPunished "Venom" BHSUThe Empire Bikes Back12910
June YinLes MissourablesThe Jeam Team12910
Rasheeq AzadMindgoblin of Little HobbesSAYYID QUTB, DRIVING THE LONGEST CAR YOU’VE EVER SEEN THROUGH TAHRIR SQUARE13610
Dylan MinarikAre You There, Chat? It's Me, MargaretLying on a Mattress at Lou’s Apartment in Pilsen, Chicago15010
Kevin YeBerkeley Mafia and the Chicago BoyFirst Cause, First Cause, make me young!1530
Arya KarthikCharlotte's Moderately Successful TeamRead slowly: A A A A A A A A A A A A A A A Read quickly: A15310
Natan HoltzmanLisan al-QuibAMOGH QUIZ HACK? 英雄联盟 400 PPG 24 TUH15310
Rohan Khervar merchantsgenAI this, genAI that, have you found your 真爱 yet15310
Nikhil DesaiFirst Cause, First Cause, make me young!Berkeley Mafia and the Chicago Boy1530