This ligand is reversibly bound by solvated derivatives of a complex derived from cobalt and the salen ligand known as salcomine. This bridging ligand links together two copper(I) (“copper-one”) centers in a superfamily of proteins that contains hexamerins. The reversible binding of this molecule in a side-on fashion induces a color change from yellow to orange in Vaska’s complex. In one complex, binding of this molecule above the plane draws the metal center away from a proximal histidine residue and induces diamagnetism. This molecule, whose binding curve follows a sigmoidal shape on the original Hill plot, has a binding affinity over 200 times weaker than that of carbon monoxide for one complex. For 10 points, name this molecule transported by hemoglobin. ■END■
| 2024 ACF Winter at Brandeis | 2024-11-16 | Y | 8 | 100% | 0% | 13% | 115.88 |
| 2024 ACF Winter at Lehigh | 2024-11-16 | Y | 7 | 86% | 0% | 29% | 100.00 |
| 2024 ACF Winter at Northwestern | 2024-11-16 | Y | 1 | 100% | 0% | 100% | 119.00 |
| 2024 ACF Winter at Ohio State | 2024-11-16 | Y | 1 | 0% | 0% | 100% | 0.00 |
| 2024 ACF Winter at UBC | 2024-11-16 | Y | 1 | 0% | 0% | 100% | 0.00 |
| Player | Team | Opponent | Buzz Position | Value |
|---|---|---|---|---|
| Neal Joshi | WashU B | UIUC A | 54 | -5 |
| Geoffrey Wu | Columbia A | Penn A | 67 | -5 |
| Rachel Fanous | Michigan A | Ohio State A | 71 | -5 |
| Arjun Bothra | Haverford A | Johns Hopkins B | 80 | 10 |
| Yixi Yang | Yale A | Yale B | 88 | 10 |
| Srikar Venkatesan | Penn B | Bard A | 88 | 10 |
| Russell Nip | UBC A | UW A | 88 | -5 |
| Jack Yesner | Carabrandeis | Bowdoin B | 92 | -5 |
| Rahul Rao-Pothuraju | Rowan A | Columbia B | 93 | -5 |
| David Bass | Johns Hopkins A | Penn State A | 94 | 10 |
| Robert Wang | Penn State B | Princeton A | 99 | 10 |
| Calvin Bostleman | Ohio State A | Michigan A | 110 | 0 |
| Rajat Sethi | Northeastern A | Williams A | 119 | 10 |
| Patrick Rivas-Giorgi | Columbia B | Rowan A | 119 | 10 |
| Michael Hunding | UIUC A | WashU B | 119 | 10 |
| Cindy Zhou | Boston University B | Brandeises Brew | 120 | 10 |
| Riley Roessler | Bowdoin A | Tufts B | 120 | 10 |
| Graham Lucas | Bowdoin B | Carabrandeis | 120 | 10 |
| Graham Close | Boston University A | Brown A | 120 | 10 |
| John Cha | Tufts A | Clark A | 120 | 10 |
| Andres Cordoba | Yale C | Diamond Brandeis | 120 | 10 |
| Vishal Kanigicherla | Penn A | Columbia A | 120 | 10 |
| Alex Wong | Rutgers A | Lehigh A | 120 | 0 |
| Will Hollister | Lehigh A | Rutgers A | 120 | 0 |
| Sophie Higgs | UW A | UBC A | 120 | 0 |