Question

This ligand is reversibly bound by solvated derivatives of a complex derived from cobalt and the salen ligand known as salcomine. This bridging ligand links together two copper(I) (“copper-one”) centers in a superfamily of proteins that contains hexamerins. The reversible binding of this molecule in a side-on fashion induces a color change from yellow to orange in Vaska’s complex. In one complex, binding of this molecule above the plane (-5[1])draws the metal center (-5[1])away from a proximal histidine residue and induces diamagnetism. (10[1])This molecule, whose binding curve follows a sigmoidal (10[1]-5[1])shape on the original Hill (-5[1])plot, (10[1])has a binding affinity over (10[1])200 times weaker than that of carbon monoxide for one complex. (0[1])For 10 points, name this molecule transported by hemoglobin. (10[1])■END■ (10[1]0[3])

ANSWER: dioxygen [or O2; accept peroxide or peroxo or O2 two-minus; reject “oxo” or “O”] (The second line refers to hemocyanins.)
<Chemistry>
= Average correct buzz position

Summary

2024 ACF Winter at Lehigh2024-11-16Y786%0%29%100.00
2024 ACF Winter at Ohio State2024-11-16Y10%0%100%0.00
2024 ACF Winter at UBC2024-11-16Y10%0%100%0.00

Buzzes

PlayerTeamOpponentBuzz PositionValue
Geoffrey WuColumbia APenn A67-5
Rachel Fanous (DII)Michigan AOhio State A (UG)71-5
Arjun BothraHaverford AJohns Hopkins B8010
Srikar VenkatesanPenn BBard A8810
Russell Nip (UG)UBC AUW A88-5
Rahul Rao-PothurajuRowan AColumbia B93-5
David BassJohns Hopkins APenn State A9410
Robert WangPenn State BPrinceton A9910
Calvin Bostleman (UG)Ohio State A (UG)Michigan A1100
Patrick Rivas-GiorgiColumbia BRowan A11910
Vishal KanigicherlaPenn AColumbia A12010
Alex WongRutgers ALehigh A1200
Will HollisterLehigh ARutgers A1200
Sophie Higgs (DII)UW AUBC A1200