Question

This ligand is reversibly bound by solvated derivatives of a complex derived from cobalt and the salen ligand known as salcomine. This bridging ligand links together two copper(I) (“copper-one”) centers in a superfamily of proteins that contains hexamerins. The reversible binding of this molecule in a side-on fashion induces a color change from yellow to orange in Vaska’s complex. In one complex, binding of this molecule above the plane (-5[1])draws the metal center (-5[1])away from a proximal histidine residue and induces diamagnetism. (10[1])This molecule, whose binding curve follows a sigmoidal (10[2]-5[1])shape on the original (-5[1])Hill (-5[1])plot, (10[1])has a binding affinity over (10[1])200 times weaker than that of carbon monoxide for one complex. (0[1])For 10 points, name this molecule transported by hemoglobin. (10[2])■END■ (10[7]0[3])

ANSWER: dioxygen [or O2; accept peroxide or peroxo or O2 two-minus; reject “oxo” or “O”] (The second line refers to hemocyanins.)
<Chemistry>
= Average correct buzz position

Summary

2024 ACF Winter at Lehigh2024-11-16Y786%0%29%100.00
2024 ACF Winter at Ohio State2024-11-16Y10%0%100%0.00
2024 ACF Winter at UBC2024-11-16Y10%0%100%0.00
2024 ACF Winter at Brandeis2024-11-16Y8100%0%13%115.88

Buzzes

PlayerTeamOpponentBuzz PositionValue
Geoffrey WuColumbia APenn A67-5
Rachel Fanous (DII)Michigan AOhio State A (UG)71-5
Arjun BothraHaverford AJohns Hopkins B8010
Srikar VenkatesanPenn BBard A8810
Russell Nip (UG)UBC AUW A88-5
Yixi YangYale AYale B8810
Jack YesnerCarabrandeisBowdoin B92-5
Rahul Rao-PothurajuRowan AColumbia B93-5
David BassJohns Hopkins APenn State A9410
Robert WangPenn State BPrinceton A9910
Calvin Bostleman (UG)Ohio State A (UG)Michigan A1100
Patrick Rivas-GiorgiColumbia BRowan A11910
Rajat SethiNortheastern AWilliams A11910
Vishal KanigicherlaPenn AColumbia A12010
Alex WongRutgers ALehigh A1200
Will HollisterLehigh ARutgers A1200
Sophie Higgs (DII)UW AUBC A1200
Cindy ZhouBoston University BBrandeises Brew12010
Riley RoesslerBowdoin ATufts B12010
Graham LucasBowdoin BCarabrandeis12010
Graham CloseBoston University ABrown A12010
John ChaTufts AClark A12010
Andres CordobaYale CDiamond Brandeis12010