Question

CHCA, HPA, and ATT crystals are common supports for instances of this technique whose analytes are highly susceptible to damage. Analytes are (-5[1])heated in a vacuum in a version of this technique that relies on blackbody infrared radiative dissociation. Performing this technique on aromatic analytes can (10[1])result in the formation of an unstable tropylium (10[4])(“tro-PILL-ee-um”) ion. (10[5])Samples for this technique can be prepared via desorption from a matrix (10[1])made (10[1])of an aromatic (10[1])acid (10[1])such as (10[1])sinapinic acid. (10[2])Analytes undergo soft ionization by either electrospray (10[1])ionization (10[1])or (10[1])MALDI (10[1])(“MALL-dee”) in (10[1])the first (10[1])step (10[1])of this technique. (10[3])The kinetic (10[1])energy of analytes in this technique (10[1])is measured in its “time of flight” variant. (10[1])For 10 points, name this technique that measures an analyte’s mass-to-charge ratio. (10[1])■END■ (10[8]0[4])

ANSWER: mass spectrometry [or MS; accept tandem mass spectrometry; accept time of flight mass spectrometry; prompt on ionization, soft ionization, MALDI, or electrospray ionization until read by asking “what larger technique is that a part of?”]
<Chemistry>
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Buzzes

PlayerTeamOpponentBuzz PositionValue
Enoch YuenImperial AEdinburgh21-5
Rasheeq Azad (UG)UNC B (UG)Duke A (UG)4510
Michał GerasimiukStanford AStanford B5310
Derek Chen (UG)Columbia CJohns Hopkins5310
Geoffrey Wu (UG)Columbia ARowan5310
Andrew HannaPennNYU B5310
Michael Eng (UG)UNC C (UG)Liberty B (DII)5410
Aswath KaraiMichigan State AAppalachian State5410
Ryan HumphreyTexas ASorbonne5410
Arjun Bothra (UG)HaverfordNYU A5410
Linus LuuCambridge COxford C5410
Rohan ShelkeBerkeley BStanford C6610
Rachel BenthamCambridge BCambridge A6710
Jacob RobertsonOxford AWarwick7010
Hansen JinBerkeley ABerkeley C7110
Russell NipUBC AClaremont A7310
Alexander HarmataMichigan AOhio State A7510
Amogh KulkarniGeodesicKentucky7510
Munir Siddiqui (UG)Maryland B (UG)UNC A (Grad)8210
Andrew FisherSheffieldKCL8310
Alexander BakerOxford BDurham B8410
Caleb Kendrick (Grad)Maryland A (Grad)JMU B (UG)8510
Rohan DalalGeorgia Tech BGeorgia Tech A8610
Kenny Zhang (UG)Virginia A (UG)GWU B (Grad)8810
Jack LewisMTSUVanderbilt B8910
Shantanu ThoratTexas A&M AIowa B9210
Sam Macchi (DII)VassarJohn Jay9210
Sam MooreDurham AImperial B9210
Abigail ZimmermanIowa ARice A9410
Ian DewanKielBristol10010
Dimitris KalafatisTexas A&M BUW A10810
Ashley CrawfordHardingSouth Carolina12010
Cade ReinbergerRIT BBinghamton12110
Julian BushlowCornell CRIT A12110
Yared TadesseCornell ACornell B12110
Perry O'Connor (Grad)Liberty A (Grad)Liberty C (DII)12110
Zander Werner (DII)Virginia C (UG)William & Mary A (UG)1210
Andrew Amygdalos (UG)GWU A (UG)Maryland C (DII)1210
Brian Dudley (UG)William & Mary A (UG)Virginia C (UG)12110
Iris Pardue (UG)KenyonCedarville12110
Mitchell IndekMichigan CMichigan B1210
Dennis Yang (DII)Michigan BMichigan C1210
Ben Russell JonesEdinburghImperial A12110
Bryanna ShaoVanderbilt AAlabama12110