Question

This mechanism obeys a geometric distribution that flattens until conversion plateaus around 90 percent. In a result that anticipated percolation theory, this mechanism’s products change when alpha is above the reciprocal of “functionality minus one.” A reaction obeying this mechanism is driven is by ethylene release in acyclic diene (“DY-een”) metathesis. (-5[1])This mechanism ideally consumes all starting materials in the first interval and increases (-5[1])average mass exponentially over time. The progress of reactions (-5[1])with this mechanism was related to number-average size by Wallace (-5[1])Carothers (10[2]-5[3])(“kuh-RUH-thers”). Reactions (-5[2])with this mechanism are never “living,” (-5[2])as they will terminate (10[1]-5[1])without aid. (-5[1])This mechanism incorporates heteroatoms (“hetero-atoms”) into molecular backbones and (-5[1])creates polyesters. (10[1])For 10 points, name this mechanism in which oligomers (-5[1])(“oh-LIG-oh-mers”) condense to form polymers, in contrast to a “chain” (10[1])method. (10[4])■END■ (10[9]0[6])

ANSWER: step-growth polymerization [or step polymerization; accept condensation polymerization until “condense” is read; prompt on polymerization until “polymers” is read; prompt on esterification until “polyesters” is read]
<Chemistry>
= Average correct buzz position

Summary

2024 ACF Nationals2024-04-21Y2475%0%63%117.00

Buzzes

PlayerTeamOpponentBuzz PositionValue
Andrew WangIllinoisBerkeley A49-5
Tiffany ZhouFloridaOttawa62-5
Andrew SalijNorthwesternMichigan71-5
Vincent DuNorth Carolina AMinnesota A81-5
Matt SchiavonePurdueChicago A8210
Bryan UgazArizona StateDuke8210
Adam FineChicago APurdue82-5
Connor BlakeChicago BTexas82-5
Andrew HannaPennToronto B82-5
Geoffrey WuColumbia ACornell A83-5
Jason HongBrownIowa State83-5
Paul LeeWUSTL AIndiana89-5
Kushal AluruRutgersVirginia89-5
Sinecio MoralesJohns HopkinsToronto A9310
Amith PunyalaWUSTL BYale B93-5
Derek ChenColumbia BClaremont Colleges95-5
Michal GerasimiukStanfordWaterloo103-5
Aidan FeinVanderbiltChicago D10510
Rohan ShelkeBerkeley BHarvard114-5
Arunn SankarGeorgia TechNYU12310
Fred GarveyTruman StateCornell B12410
Max HodesChicago CKentucky12410
Kenny ZhangVirginiaRutgers12410
Kevin ParkClaremont CollegesColumbia B12410
Gabrielle ClarkOttawaFlorida12510
Shahar SchwartzBerkeley AIllinois12510
Eric GunterNorth Carolina BMcGill12510
Matthew SiffYale AMaryland12510
Yashwanth BajjiMichiganNorthwestern1250
Ethan AshbrookMinnesota ANorth Carolina A12510
Richard NiuCornell AColumbia A1250
Joy AnHarvardBerkeley B12510
Jason ZhangToronto BPenn12510
Liam KusalikWaterlooStanford12510
Chinmay MurthyTexasChicago B12510
Urbas EkkaMinnesota BSouth Carolina1250
Khushi UmarwadiaSouth CarolinaMinnesota B1250
Alex AkridgeIndianaWUSTL A1250
Lydia TarekegnYale BWUSTL B1250