Question

An atom of this element sits at the center of the BCC unit cell of a Heusler (“HOYSE-ler”) alloy. This metal was doped into gallium nitride to form the first ferromagnetic semiconductor used in spintronics; similarly, a complex oxide containing twelve atoms of this spin-5/2 (“spin-five-halves”) metal was the first-known single-molecule magnet. (10[1])After reactions in acidic, neutral, and basic solutions, this element respectively speciates into +2 (“plus-2”), +4 (“plus-4”), and +6 (-5[1])(“plus-6”) oxidation states. Spinel oxide cathodes containing this metal, instead of cobalt, intercalate lithium in a commercial lithium battery and are reduced by zinc in a commercial alkaline battery. An oxide cluster containing this element and calcium (-5[1])splits water in the photosynthetic (10[2]-5[1])oxygen-evolving (10[2])complex. (10[2])This metal’s brown-colored (10[2])dioxide (10[3])precipitates when double (-5[1])bonds react with its +7 (“plus-7”) oxidation (10[1])state. (10[2]-5[1])For 10 points, name this transition metal found in a strong violet-colored (10[1])oxidizing agent. (10[1])■END■ (10[3]0[1])

ANSWER: manganese [or Mn; accept manganese dioxide or MnO2] (The violet-colored oxidizing agent is potassium permanganate.)
<Chemistry>
= Average correct buzz position

Summary

2023 ACF Nationals04/22/2023Y2195%0%24%115.70

Buzzes

PlayerTeamOpponentBuzz PositionValue
Arya KarthikGeorgia Tech AMichigan A4910
Dan NiCornell BClaremont A66-5
Jonathan LauJohns Hopkins AIowa State A102-5
Pranav SivaramOhio State AUC Berkeley B10710
Andrew HannaVanderbilt AMinnesota A10710
Tracy MirkinFlorida AWUSTL A107-5
Geoffrey ChenCornell ANorth Carolina A10810
June YinWUSTL BMcGill A10810
Caleb KendrickMaryland AChicago A10910
Joelle SmartRutgers APenn A10910
Sharath NarayanNorthwestern AGeorgia Tech B11210
Daniel YangChicago BImperial A11210
Eric WolfsbergStanford AMinnesota B11310
Daniel MaYale ARutgers B11310
Karan GurazadaTexas AColumbia A11310
Shahar SchwartzUC Berkeley AVirginia A116-5
Ani PerumallaPenn State ADuke A12210
Isak JatoiSouth Carolina AIndiana A12310
Nat KuNYU ABrown A123-5
Alan XieYale BToronto A12310
Tiffany ZhouFlorida BIllinois A13510
David BassVirginia AUC Berkeley A13710
Kevin ParkClaremont ACornell B13810
Paul LeeWUSTL AFlorida A13810
JD KrothIowa State AJohns Hopkins A1380
Jason HongBrown ANYU A13810