An atom of this element sits at the center of the BCC unit cell of a Heusler (“HOYSE-ler”) alloy. This metal was doped into gallium nitride to form the first ferromagnetic semiconductor used in spintronics; similarly, a complex oxide containing twelve atoms of this spin-5/2 (“spin-five-halves”) metal was the first-known single-molecule magnet. After reactions in acidic, neutral, and basic solutions, this element respectively speciates into +2 (“plus-2”), +4 (“plus-4”), and +6 (“plus-6”) oxidation states. Spinel oxide cathodes containing this metal, instead of cobalt, intercalate lithium in a commercial lithium battery and are reduced by zinc in a commercial alkaline battery. An oxide cluster containing this element and calcium splits water in the photosynthetic oxygen-evolving complex. This metal’s brown-colored dioxide precipitates when double bonds react with its +7 (“plus-7”) oxidation state. For 10 points, name this transition metal found in a strong violet-colored oxidizing agent. ■END■
ANSWER: manganese [or Mn; accept manganese dioxide or MnO2] (The violet-colored oxidizing agent is potassium permanganate.)
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